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New xarray ver supports this keyword.
I think allow_rechunk might be good or expose this option to the call e.g. xr.rmse(dask_gufunc_kwargs={...})
http://xarray.pydata.org/en/stable/generated/xarray.apply_ufunc.html
dask_gufunc_kwargs (dict, optional) – Optional keyword arguments passed to dask.array.apply_gufunc if dask=’parallelized’. Possible keywords are output_sizes, allow_rechunk and meta.