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Set of Standard Solutions For Calibration Curve

The document contains data from standard solutions used to generate a calibration curve for determining the equilibrium constant (Kc) for the reaction of iron(III) and thiocyanate. Test solutions were prepared with varying concentrations of iron(III) and thiocyanate and their absorbances measured. The calibration curve was used to determine the equilibrium concentrations of the complex ion (FeNCS2+), which were then used to calculate Kc values for each test solution. The average Kc, standard deviation, and percent relative standard deviation were reported.

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23 views

Set of Standard Solutions For Calibration Curve

The document contains data from standard solutions used to generate a calibration curve for determining the equilibrium constant (Kc) for the reaction of iron(III) and thiocyanate. Test solutions were prepared with varying concentrations of iron(III) and thiocyanate and their absorbances measured. The calibration curve was used to determine the equilibrium concentrations of the complex ion (FeNCS2+), which were then used to calculate Kc values for each test solution. The average Kc, standard deviation, and percent relative standard deviation were reported.

Uploaded by

gatedsprint
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd
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SET OF STANDARD SOLUTIONS FOR CALIBRATION CURVE

Molar concentration of Fe(NO3)3


STANDARD SOULTIONS

Molar concentration of NaSCN

0.2

0.001

BLANK

1*

A.1

Volume of NaSCN (mL)

A.2

Moles of SCN-

1.00E-06

2.00E-06

3.00E-06

4.00E-06

5.00E-06

A.3

[SCN-] (25.0 mL)

4.00E-05

8.00E-05

1.20E-04

1.60E-04

2.00E-04

A.4

[FeNCS2+] (mol/L)

4.00E-05

8.00E-05

1.20E-04

1.60E-04

2.00E-04

A.5

ABSORBANCE

0.285

0.472

0.706

1.09

1.14

* Show all calculations for standard #1 in space below

0.9

CALIBRATION CURVE
f(x) = 0.2385428571x - 0.2194

0.8

0.7

0.6

0.5
ABSORBANCE
0.4

0.3

0.2

0.1

0
0

0.00004

0.00008

0.00012

0.00016

Concentration of FeNCS2+ (mol/L)

0.0002

PART B - ABSORBANCE FOR TEST SOLUTIONS


Molar concentration of Fe(NO3)3 (read bottle)

0.002

TEST SOULTIONS

10

5.00

5.00

5.00

5.00

5.00

1.00E-05

1.00E-05

1.00E-05

1.00E-05

1.00E-05

1.00

2.00

3.00

4.00

5.00

2.00E-06

4.00E-06

6.00E-06

8.00E-06

1.00E-05

3.16E-01

3.22E-01

4.80E-01

7.08E-01

8.35E-01

B.1 Volume of Fe(NO3)3 (mL)


B.2 Moles of Fe+3 Initial (mol)
B.3

Volume of NaSCN (mL)

B.4

Moles of SCN- ( Initial) (mol)

B.5 Absorbance(A)

Molar concentration of NaSCN (read bottle)

0.002

* Show all calculations for Test Solution #6 in space below

PART C - CALCULATION OF KC
TEST SOULTIONS
C.1
C.2

10

[FeNCS+2], Equilibrium, from Calibration Curve

2.224

2.27

2.93

3.89

4.42

Moles of [FeNCS2+] at Equilibrium (10mL) (mol)

2.22E-02

2.27E-02

2.93E-02

3.89E-02

4.42E-02

[Fe ] at equilibrium
3+

3+
C.3 Moles of Fe reacted (mol)

2.22E-02

2.27E-02

2.93E-02

3.89E-02

4.42E-02

3+
C.4 Moles of Fe , equilibrium (mol)

-2.22E-02

-2.27E-02

-2.93E-02

-3.89E-02

-4.42E-02

-2.22E+00

-2.27E+00

-2.93E+00

-3.89E+00

-4.42E+00

10

C.5

[Fe3+ ], equilibrium unreacted (10 mL) (mol/L)

* Show all calculations for Test Solution #6 in space below

[SCN-], EQUILIBRIUM
TEST SOULTIONS
C.6 Moles of SCN- reacted (mol)
C.7 Moles of SCN-, equilibrium (mol)
C.8 [SCN- ], equilibrium unreacted (10 mL) (mol/L)

6*

2.22E-02

7
2.27E-02

2.93E-02

3.89E-02

4.42E-02

-2.22E-02

-2.27E-02

-2.93E-02

-3.89E-02

-4.42E-02

-2.22E+00

-2.27E+00

-2.93E+00

-3.89E+00

-4.42E+00

4.41E-01

3.41E-01

2.57E-01

2.26E-01

* Show all calculations for Test Solution #6 in space below

C.9 Kc =[C.1]/[C.5][C.8]

4.50E-01

* Show all calculations for Test Solution #6 in space below

C.11

AVERAGE Kc
Standard Deviation of Kc

C.12

%RSD

C.10

0.3431404012
0.0916108294
26.6977683487

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