TATA BLUESCOPE STEEL LIMITED, JAMSHEDPUR.
LIQUEFIED PETROLEUM GAS Approved By:
MATERIAL SAFETY DATA SHEET
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MATERIAL SAFETY DATA SHEET ANNEXURE VII
MATERIAL SAFETY DATA SHEET
LIQUEFIED PETROLEUM GAS
MSDS Number : S4034
Effective Date : 08.20.98
1. PRODUCT IDENTIFICATION
Synonyms : Liquefied Petroleum Gas, LPG, Bottled Gas, Cooking Gas
CAS No. : 68476
Chemical Formula : Mixture of Propane & Butane
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient CAS No. Percent Hazardous
Propane (C3H8) 74-98-6 30 approx Yes
Butanes (C4H10) 106-97-8 70 approx Yes
Ethyl mercaptan 75-08-01 0-50 ppm
3. HAZARDS IDENTIFICATION
Emergency Overview
HIGHLY FLAMMABLE GAS.
NFPA RATING (Under Fire Conditions. Does not apply to exposure hazards other than during fire):
Health Rating : 1 Slightly toxic
Flammability Rating : 4 Extremely flammable
Reactivity Rating : 0 Stable
POTENTIAL HEALTH EFFECTS
INHALATION:
At excessive vapor concentrations, this product has anesthetic, asphyxiating properties and may cause
sleepiness. At levels above 100,000 ppm (i.e. 10%), propane is mildly irritating to the respiratory tract and
may result in dizziness, headache, drowsiness, nausea, shortness of breath, muscular incoordination,
excessive salivation, disorientation, vomiting, and excitation. In extreme cases, convulsions,
Unconsciousness and death may occur as a result of asphyxiation. Persons with chronic respiratory
disease should avoid exposure.
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INGESTION:
Liquid may cause freeze burn similar to frostbite. Ingestion not expected to occur in normal use.
SKIN CONTACT:
Liquid may cause freeze burn similar to frostbite.
EYE CONTACT:
Corrosive! Causes irritation of eyes, and with greater exposures it can cause burns that may result in
permanent impairment of vision, even blindness.
4. FIRST AID MEASURES:
INHALATION:
Remove victim from further exposure and into fresh air. Provide oxygen if breathing is difficult. Give
artificial respiration if patient is not breathing. If victim is unconscious, place in the unconscious (recovery)
position. Give external cardiac massage if necessary & get prompt medical attention.
INGESTION:
If swallowed, get immediate medical attention.
SKIN CONTACT:
If freeze burn occurs, remove contaminated clothes, shoes and jewelry. Immerse burned area in warm
(not hot) water. Keep immersed. Get prompt medical attention.
EYE CONTACT:
For contact with liquid, flush immediately with water. Obtain immediate medical attention.
5. FIRE FIGHTING MEASURES:
FLAMMABILITY
LPG is gaseous and highly flammable at normal temperatures and pressures. The gas is normally stored
under pressure in the liquid form. Release of pressure is associated with rapid cooling, the intensity of
which is dependent on the rate of release. Containers of LP Gas are explosive hazards, when exposed to
excessive heat.
Flash point : : -104.40 C to – 600C
Auto-ignition temperature : : 4050C
Flammable limits in air, % by volume: : LOWER--2.2% UPPER--9.6%
Explosion sensitivity to static electricity: : May explode
Explosion sensitivity to impact: : May explode
EXPLOSION:
Uncontrolled vapors spread rapidly, as they are heavier than air and are extremely flammable
FIRE EXTINGUISHING MEDIA:
CO2, DCP & Water Spray.
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FIRE FIGHTING PROCEDURES
Eliminate sources of ignition
Evacuate area
Notify fire department
Allow only trained, properly protected Personnel in area
Shut off source of gas, if possible
Allow fire to burn itself out after gas flow is shut off
If gas flow cannot be shut off, do not extinguish fire
Allow fire to burn itself out using high volume water supply to cool heat-exposed pressure containers and
nearby equipment
Approach a flame enveloped container from the side, never the head ends
Use extreme caution when applying water to a container, which has been exposed to heat or flame for
more than a short time.
For uncontrollable fires and when flame is impinging on container, withdraw all personnel and evacuate
vicinity immediately
SPECIAL INFORMATION:
If fuel supply feeding fire cannot be stopped, allow the gas to burn under controlled conditions.
Keep the container cool by spraying water if exposed to heat or fire.
Fight fire from upwind direction.
Apply water on vapour space of container
SPILL OR LEAKS
Product is extremely flammable.
Vapor is heavier than air and may collect at lower levels.
Flammable concentrations may be present below nose level.
If there is a leak but no fire, do not ignite the escaped gas.
Eliminate all ignition sources
Do not smoke, use a nearby phone or turn electrical switches on and off.
Evacuate area.
If possible, remove leaking container to safe area.
Stop flow of gas or allow vapor to disperse in a safe area.
UNUSUAL HAZARDS
Never stand in the axis of bullets
Heavy leakage of liquid can impair visibility
LPG fires can cause severe burn injuries
Leaking gas may travel long distance till it meets an ignition source and flashback or cause vapour cloud
explosion.
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6. ACCIDENTAL RELEASE MEASURES:
Use local and dilution ventilation to maintain exposures below acceptable criteria.
If concentrations are high enough to warrant supplied-air or self-contained breathing apparatus,
atmosphere may be flammable (see Section V). Always use OSHA approved respiratory protection
(supplied-air or self-contained breathing apparatus as appropriate).
Avoid skin contact with liquid because of possibility of freeze burn. Wear gloves and protective clothing,
which are impervious to the product for the duration of the anticipated exposure.
Use chemical safety goggles meeting approved specifications when connecting or disconnecting lines
under pressure. Spectacle type safety glasses do not provide satisfactory protection.
Firefighters should wear self-contained breathing apparatus in the positive pressure mode with a full face
piece when there is a possibility of exposure to smoke, fumes or hazardous decomposition products
7. HANDLING AND STORAGE:
Store in an authorized location (outside, detached storage is preferred with adequate ventilation.
Isolate from heat and ignition sources.
Naked flame & smoking strictly prohibited
Isolate from combustible materials.
All equipment, pipelines should be properly earthed /bonded.
Provide separate storage locations for other compressed or flammable gases.
Periodically inspect/test for leaks, dents, gouges and corrosion with emphasis on bottom of cylinder.
Store cylinders in upright position or with pressure relief valves in vapor space.
Do not drop or abuse cylinders.
Keep container valve closed and plugged when not in use.
Install protective caps when cylinders are not connected for use
Empty containers retain some residue, so they should be treated as if they were full.
Gas free the containers before undertaking repairs
Laid down Safe Operating Procedures should be strictly observed
8. EXPOSURE CONTROLS/PERSONAL PROTECTION:
AIRBORNE EXPOSURE LIMITS:
MATERIAL PEL/TWA TLV/TWA
PROPANE 1000 ppm Simple Asphyxiant
BUTANE 800 ppm 800 ppm
ETHYL MERCAPTAN 0.5 ppm 0.5 ppm
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VENTILATION SYSTEM:
Use local and dilution ventilation to maintain concentrations below the exposure standard or lower
explosive limit (LEL).
PERSONAL RESPIRATORY PROTECTION:
If concentrations are high enough to warrant supplied-air or self-contained breathing apparatus,
atmosphere may be flammable (see Section V). Always use OSHA approved respiratory protection
(supplied-air or self-contained breathing apparatus as appropriate).
SKIN PROTECTION:
Avoid skin contact with liquid because of possibility of freeze burn. Wear gloves and protective clothing,
which are impervious to the product for the duration of the anticipated exposure.
EYE PROTECTION:
Use chemical safety goggles meeting approved specifications when connecting or disconnecting lines
under pressure. Spectacle type safety glasses do not provide satisfactory protection.
9. PHYSICAL AND CHEMICAL PROPERTIES:
Appearance : Colorless
Odour : Ethyl Mercaptan added for odour warning
Boiling range : -420C to 20 C
Melting point : N/A
Vapor pressure 196 psig @ 100°F
Specific gravity (water = 1) 0.562 gm/l@150C
Vapor density (air = 1) 1.8
Solubility in water : Immiscible, liquid floats & boils on water
Odorant Warning:
Odorant is added to aid in detection of leaks. One common odorant is ethyl mercaptan, CAS. No. 5-08-1.
Odorant has a foul, skunk-like odor. The odorant is effective in most instances, but not everyone can
smell the odor. The ability of people to detect odors varies widely. Also, certain chemical reactions with
material in the propane system can reduce the propane dor level. No odorant will be 100% effective in all
circumstances. If odor level appears to be weak, notify supplier immediately.
10. STABILITY AND REACTIVITY:
STABILITY:
Stable
HAZARDOUS DECOMPOSITION PRODUCTS:
Incomplete combustion may yield carbon monoxide, a toxic gas.
HAZARDOUS POLYMERIZATION:
Will not occur.
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INCOMPATIBILITIES:
Strong oxidizing agents
CONDITIONS TO AVOID:
Keep away from high heat, sparks & open flame,.
11. TOXICOLOGICAL INFORMATION :
Product is not listed by IARC, NTP or OSHA as a potential carcinogen. Propane and some of the minor
components have been reported to be cardiac sensitizers in experiments.
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL PROTECTION:
Avoid uncontrolled releases of this material
Liquid release will have possible effect on plant and animal life.
Large liquid release will quickly vaporize to produce vapor cloud.
Vapor cloud is both a fire and asphyxiation hazard.
13. DISPOSAL CONSIDERATIONS:
Water spray can be used to help dilute vapor concentration in air.
Dispose of gas in accordance with applicable laws and regulations
When permitted, vent vapor in a safe location and insure that gas dissipates below the lower flammable
limit.
Controlled burning is preferred.
14. TRANSPORT INFORMATION
Proper Shipping Name : Liquefied Petroleum Gas
Hazard Class : Flammable Gas
UN/NA : UN1075
LP Gas is classified under the Manufacture, Storage & Import of Hazardous Chemicals Rules, 1989 for
the Transport of Dangerous Goods by Road and Rail (ADG Code) as a FLAMMABLE GAS (Class
2.1). LPG must be transported in accordance with the latest edition of ADG Code (April 1987).
Large volumes must be transported in approved tankers, and smaller volumes in approved
pressure containers.
15. REGULATORY INFORMATION
HAZARD CATEGORY:
Flammable gas
SOURCE
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