Maha DPP - Thermodynamics
Maha DPP - Thermodynamics
2p
1
p
1
V
V1 3 V1
a) 3 5 5 7
b) c) d)
2 3 2
16. In a cyclic process, work done by the system is
a) Zero b) Equal to heat given to the system
c) More than the heat given to system d) Independent of heat given to the system
17. A system goes from A to B via two processes I and II as shown in figure. If ∆𝑈! and ∆𝑈" are the changes in
internal energies in the processes I and II respectively, then
Relation between ∆𝑈! and ∆𝑈" cannot be
a) ∆𝑈! = ∆𝑈" b)
determined
c) ∆𝑈" > ∆𝑈! d) ∆𝑈" < ∆𝑈!
18. A refrigerator works between temperature of melting ice and room temperature (17℃). The amount of
energy in kWh that must be supplied to freeze 1 kg of water at 0℃ is
a) 1.4 b) 1.8 c) 0.058 d) 2.5
19. A cyclic process 𝐴𝐵𝐶𝐴 is shown in the 𝑉-𝑇 diagram. Process on the 𝑃-𝑉 diagram is
V
C B
A T
a) P
b) P
c) P
d) P
C
B A
A B
A
B A C C B
C
V V V V
20. During an isothermal expansion of an ideal gas
a) Its internal energy decreases
b) Its internal energy does not change
c) The work done by the gas is equal to the quantity of heat absorbed by it
d) Both (b) and (c) are correct
21. A system is given 300 calories of heat and it does 600 𝑗𝑜𝑢𝑙𝑒𝑠 of work. How much does the internal energy
of the system change in this process (𝐽 = 4.18𝑗𝑜𝑢𝑙𝑒𝑠/𝑐𝑎𝑙)
a) 654 𝑗𝑜𝑢𝑙𝑒 b) 156.5 𝑗𝑜𝑢𝑙𝑒 c) −300 𝑗𝑜𝑢𝑙𝑒 d) −528.2 𝑗𝑜𝑢𝑙𝑒
22. A graph of pressure versus volume for an ideal gas for different processes is as shown. In the graph curve
OC represents
2p B
0
p0 A
V0 2V 0 V
30. In the indicator diagram 𝑇. , 𝑇/ , 𝑇0 , 𝑇1 represent temperature of gas at 𝐴, 𝐵, 𝐶, 𝐷 respectively. Which of the
following is correct relation?
a) 𝑇. = 𝑇/ = 𝑇0 = 𝑇1 b) 𝑇. ≠ 𝑇/ ≠ 𝑇0 ≠ 𝑇1
c) 𝑇. = 𝑇/ and 𝑇0 = 𝑇1 d) None of these
31. An ideal gas is allowed to expand freely against a vacuum in a rigid insulated container. The gas undergoes
a) An increase in its internal energy b) A decrease in its internal energy
c) Neither an increase nor a decrease in its d) A decrease in temperature
temperature or internal energy
32. What is the nature of change in internal energy in the following three thermodynamical processes shown
in figure?
a) ∆𝑈 is positive in all the three cases
b) ∆𝑈 is negative in all the three cases
c) ∆𝑈 is positive for (i), negative for (ii), zero for (iii)
d) ∆𝑈 = 0, in all the cases
33. A cyclic process for 1 mole of an ideal gas is shown in figure in the 𝑉-𝑇, diagram. The work done in 𝐴𝐵, 𝐵𝐶
and 𝐶𝐴 respectively
V
C
V2
V1 A
B
O T
T1 T2
𝑉! 𝑉!
a) 0, 𝑅𝑇" ln ƒ „ , 𝑅(𝑇! − 𝑇" ) b) 𝑅(𝑇! − 𝑇" ), 0, 𝑅𝑇! ln
𝑉" 𝑉"
𝑉" 𝑉"
c) 0, 𝑅𝑇" ln ƒ „ , 𝑅(𝑇! − 𝑇" ) d) 0, 𝑅𝑇" ln ƒ „ , 𝑅(𝑇" − 𝑇! )
𝑉! 𝑉!
34. A gas is suddenly compressed to ¼ th of its original volume at normal temperature. The increase in its
temperature is (𝛾 = 1.5)
a) 273 K b) 573 K c) 373 K d) 473 K
35. In a reversible isochoric change
a) ∆𝑊 = 0 b) ∆𝑄 = 0 c) ∆𝑇 = 0 d) ∆𝑈 = 0
36. Initial pressure and volume of a gas are 𝑃 and 𝑉 respectively. First it is expanded isothermally to volume
4𝑉 and then compressed adiabatically to volume 𝑉. The final pressure of gas will be (given 𝛾 = 3/2)
a) 1𝑃 b) 2𝑃 c) 4𝑃 d) 8𝑃
: HINTS AND SOLUTIONS :
1 (b) 𝑝𝑉 " = constant …(i)
In isothermal process, heat is released by the gas
to maintain the constant temperature Gas equation is ,
2 (a) pV=RT
For adiabatic process
)*
" ⇒ 𝑝= …(ii)
𝑃! 𝑉! = 𝑝# 𝑉# ,
𝑅𝑇! " 𝑅𝑇# " From Eqs. (i) and (ii), we obtain
𝑉 = 𝑉
𝑉! ! 𝑉# # 𝑅𝑇
m n 𝑉 " = constant
"$! "$! 𝑉
𝑇! 𝑉! = 𝑇# 𝑉#
3 (d) ⇒ 𝑇𝑉 "$! = constant …(iii)
For adiabatic forces ∆𝑊 = −∆𝑈 [∵ ∆𝑄 = 0]
!
⇒ ∆𝑊 = −(−50) = +50𝐽 But 𝑇∝ (given)
√,
4 (a)
As work done=0 as 𝑇𝑉 !/# = constant …(iv)
𝑄 = ∆𝑈 + 𝑝∆𝑉 ⇒ 𝑇# = 2𝑇!