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I'm extracting this from #75
In MathML 3, percentages are relative to the size of the mpadded element.
For example with
<mpadded width="50%">
<mspace width="100px"/>
</mpadded>
the mpadded would have width=50px. As stated on #75, this behavior is different from CSS and makes implementation more complicate. So percentage values are just ignored in Chrome 109 implementation.
Currently, https://w3c.github.io/mathml-core/#adjust-space-around-content-mpadded does not seem to say how percentage values are handled.